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• W2060983232 endingPage "2900" @default.
• W2060983232 startingPage "2887" @default.
• W2060983232 abstract "Local probe oxidation experiments by conductive AFM have been performed on a hexadecyl monolayer and a N-hydroxysuccinimide (NHS)-ester-functionalized undecyl (NHS-UA) monolayer assembled on hydrogen-terminated (i.e., unoxidized) silicon. The oxidation conditions for the mild oxidation of the top terminal groups of monolayers and the deep oxidation of the underlying silicon into silicon oxide were investigated. The results show that the bias threshold for the AFM tip-induced oxidation of the top groups of monolayers on oxide-free silicon can be reduced by 2 V for the methyl-terminated hexadecyl monolayer and even by 3.5 V for the active NHS-ester-terminated undecyl monolayer, in comparison to a methyl-terminated octadecyl trichlorosilane (OTS) monolayer on oxidized silicon. Upon such local mild oxidation, the active NHS ester group of the NHS-UA monolayer is selectively cleaved off to generate carboxyl-containing monolayer nanopatterns, opening further possibilities for subsequent patterned multifunctionalization." @default.
• W2060983232 created "2016-06-24" @default.
• W2060983232 creator A5004429988 @default.
• W2060983232 creator A5014797149 @default.
• W2060983232 creator A5044512586 @default.
• W2060983232 creator A5055120115 @default.
• W2060983232 creator A5070808413 @default.
• W2060983232 date "2009-09-16" @default.
• W2060983232 modified "2023-09-23" @default.
• W2060983232 title "Local Probe Oxidation of Self-Assembled Monolayers on Hydrogen-Terminated Silicon" @default.
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• W2060983232 doi "https://doi.org/10.1021/nn9007059" @default.
• W2060983232 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19754133" @default.
• W2060983232 hasPublicationYear "2009" @default.
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• W2060983232 hasAuthorship W2060983232A5044512586 @default.

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