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- W2060996910 abstract "The hydrolysis of Th4+ has been studied in a 1 M perchlorate medium at 25°C by electrometric titrations. The hydrogen ion concentration was measured with quinhydrone or hydrogen electrodes. It can be deduced from the equilibrium data that a series of complexes Th((OH)3Th)n or rather are formed with n = 1, 2, 3 etc. No upper limit for n was found and it was concluded that there must be complexes in the solutions with n values greater than 6. To a good approximation the data may be interpreted by the assumption that the equilibrium constants for all successive steps are the same, k = 10−7.50 (mechanism IIIa with ko = 1, Acta Chem Scand. 8, 318-335 (1954). The data agree well with thos published by Kraus and Holmberg (1954), although the conclusions differ somewhat. The hydrolysis of U4+ has been studied in a 3 M perchlorate medium at the same temperature. Hydrogen and glass electrodes were used for the pH measurements. The data indicate that complexes are formed first with n = 1; at higher degrees of hydrolysis, larger complexes are formed, some with n > 3." @default.
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- W2060996910 date "2010-09-02" @default.
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- W2060996910 title "The mechanism of thorium IV and uranium IV hydrolysis" @default.
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