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- W2060999011 abstract "Abstract The syntheses and selected structure–property relationships of two series of polycarbosiloxanes (HB-PCSOX) and polycarbosilanes (HB-PCS) prepared by the platinum-catalyzed bimolecular non-linear hydrosilylation polymerizations of commercially available 1,3-diallyl- or 1,3-divinyl- disiloxanes or disilanes and tri- or tetra-functional siloxysilanes or silanes (i.e., A x + B y polymerization systems where x = 2 and y = 3 or 4) are described. The polymerizations were controlled to avoid gelation and ensure preparation of non-crosslinked soluble polymer products by adjusting the molar ratios of the reacting A (allylsilyl, Si–CH 2 –CH CH 2 , or vinylsilyl, Si–CH CH 2 ) and B (silyl, Si–H) reactive functional groups such that r ≤ 1/[( x − 1)( y − 1)] or r ≥ ( x − 1)( y − 1) where r = [A]/[B]. The polymers were characterized by IR, 1 H, 13 C and 29 Si NMR, SEC, DSC and TGA. Their molecular weights were found to increase in the following order of the side-group substitution in the 1,3-divinyldisiloxane monomer used: EtO > Me > MePh > Ph 2 , consistent with the increased electron-donation to the vinyl groups causing their increased reactivity in hydrosilylation. These polymers represent unique yet easily and economically available multifunctional nanoscopic dendritic building blocks for more complex 3D nano-structured materials for a variety of applications in electronics, photonics, lithography, specialty coatings, etc." @default.
- W2060999011 created "2016-06-24" @default.
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- W2060999011 date "2012-11-01" @default.
- W2060999011 modified "2023-10-16" @default.
- W2060999011 title "Hyperbranched polycarbosiloxanes and polycarbosilanes via bimolecular non-linear hydrosilylation polymerization" @default.
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- W2060999011 doi "https://doi.org/10.1016/j.polymer.2012.09.052" @default.
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