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- W2061014412 abstract "Abstract The anodic behaviour of pure tin and a Pb-10wt.%Sn alloy have been studied in sulfuric acid solutions using the ring-disk technique and potential decay measurements. For Sn in H 2 SO 4 the results show that this metal passivates partly at acid concentrations above 3 M. Tin was found to dissolve mainly as Sn(II) ions, but to some extent also as Sn(IV) if the potential is > 3 V. The ex situ analysis of the corrosion layer formed on pure Sn showed that the layer consisted mainly of amorphous SnO. The results for the Pb-Sn alloy showed that Sn dissolves from or through the corrosion layer formed on the alloy as Sn(II) ions. Tin was found to inhibit the formation of PbO 2 . The effect of Sn ions dissolved in the solution seemed to be similar to that of Sn as an alloying agent. The ring-disk voltammetric measurements showed that a tin-containing compound is formed on the Pb-Sn alloy. This product is probably a mixed Pb-Sn oxide or tin-doped PbO n ." @default.
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- W2061014412 date "1992-12-01" @default.
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- W2061014412 title "The anodic behaviour of tin and a lead-tin alloy in sulfuric acid" @default.
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- W2061014412 doi "https://doi.org/10.1016/0378-7753(92)80054-f" @default.
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