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- W2061025995 abstract "Abstract Physical and electrochemical properties of the AlBr3/MBr/ArH system with different metal ions added were studied. Nernst plots for the Hg/Hg2+ and Zn/Zn2+ couples were measured and the formal potentials were found to be 0.65–0.68 V (RAIE) for the former and 0.08 V (RAIE) for the latter. The slopes of the Nernst plots were 29±1 mV as expected. The exchange current density for deposition and dissolution of mercury was found to be 18.5 μA cm−2 and 73 μA cm−2 in 0.1 mM and 1.0 mM solutions of HgBr2, respectively, The density of the solution was found to increase linearly with increasing concentration of AlBr3, and its values in toluence and mesitylene were practically identical. The viscosity increased rapidly from a value of ca. 0.5–0.6 cP for the pure solvents to 1.9 cP and 4.0 cP for 2.3 M AlBr3, 0.76 M KBr in toluence and mesitylene, respectively. The measured diffusion coefficients of Hg2+ were in the range of (0.8–2.0)×10−6 cm2s−1 in mesitylene (depending on the concentration of AlBr3 and KBr) and 4.0×10−6 cm2s− in toluene. The calculated ionic radius was 6.3±1 A in mesitylene and 2.3±0.5 A in toluene. The diffusion coefficient for Ag+, ions was found to have similar values. The specific conductivity was found to increase with concentration of (KAl2Br7). The molar conductivity also increases with increasing concentration. When corrected for the change of viscosity, the normalized molar conductivity increases linearly with the square of the concentration of (KAl2Br7). A detailed survey of existing literature data for this and similar systems is presented." @default.
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- W2061025995 date "1977-01-01" @default.
- W2061025995 modified "2023-09-25" @default.
- W2061025995 title "Electrochemical properties of the AlBr3/MBr/ArH solvent system and polarography of metal ions in it" @default.
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- W2061025995 doi "https://doi.org/10.1016/s0022-0728(77)80208-8" @default.
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