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• W2061041567 abstract "The improved reverse Monte Carlo simulations of the structure of vitreous P2O5 are constrained by neutron and x-ray scattering data both covering large ranges of momentum transfer, and by geometric constraints which are different for the terminal and bridging oxygen sites. The analysis of the model structures reveals the anisotropy of the threefold-linked PO4 tetrahedra with different P-O bonds and O-O edges of the terminal and bridging oxygen sites. The O-P-O and P-O-P bond angles possess mean values of 109 and 139°. Flattened network cages formed of the P atoms and the bridging O sites are identified in the models. Their formation is enhanced by the more real geometry of the PO4 units. The first peak of the x-ray and neutron diffraction data is related to the lateral dimension of the cages of about 0.47 nm." @default.
• W2061041567 created "2016-06-24" @default.
• W2061041567 creator A5081356449 @default.
• W2061041567 date "2000-09-26" @default.
• W2061041567 modified "2023-10-17" @default.
• W2061041567 title "A refined reverse Monte Carlo analysis of the structure of vitreous P₂O₅" @default.
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• W2061041567 doi "https://doi.org/10.1088/0953-8984/12/41/306" @default.
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