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- W2061063122 abstract "Evidence is presented which demonstrates that the Hg2+- and NO+-induced aquations of t-[Co(tren)(NH3)Cl]2+,(1), and t-[Co(tren)(NH3)(N3)]2+, (2), respectively, follow different paths; i.e. that a common intermediate of the type [Co(tren)(NH3)]3+ is not involved [tren = 2,2′,2″-triaminotriethylamine, N(CH2CH2NH2)3]. Saturation entry of NO3– to form t-[Co(tren)(NH3)(NO3)]2+(3) occurs as [NO3–] is raised to 1 mol dm–3[48% for (1); 35% for (2)] and this limiting condition is interpreted in terms of pre-formed ion pairs (Kipca. 5 dm3 mol–1). Second-order rate constants for the Hg2+-induced reaction of p-[Co(tren)(NH3)Cl]2+ and t-[Co(tren)(NH3)Cl]2+, are 5.6 ± 0.2 and 9.7 ± 0.1 dm3 mol–1s–1 respectively." @default.
- W2061063122 created "2016-06-24" @default.
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- W2061063122 date "1980-01-01" @default.
- W2061063122 modified "2023-09-24" @default.
- W2061063122 title "Mercury(II)- and nitrosyl-induced aquation of anionopenta-aminecobalt-(III) species. Reactions of the t-[Co{N(CH2CH2NH2)3}(NH3)X]2+ions (X = Cl–or N3–) and the importance of ion pairs" @default.
- W2061063122 doi "https://doi.org/10.1039/dt9800002255" @default.
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