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- W2061082364 abstract "A study of the structures preferred by the M2X2 rings in the dinuclear complexes of late transition metals of types [M2(μ-XR2)2L2] and [M2(μ-XR3)2L2] is presented, based on qualitative orbital arguments supported by DFT calculations on model compounds. The main conclusions agree well with the results of a structural database analysis. With the simplified electron counting scheme applied, complexes with six or four electrons available for bonding of the M2X2 framework are predicted to have two possible minimum energy structures, with either a short M–M or X–X distance, whereas compounds with eight framework electrons are expected to present no short through-ring distance. Such behavior is consistent with the framework electron counting rules reported earlier for compounds with different coordination spheres and provides a general description of the structure and bonding in a variety of compounds with M2X2 diamonds." @default.
- W2061082364 created "2016-06-24" @default.
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- W2061082364 date "2002-04-11" @default.
- W2061082364 modified "2023-10-18" @default.
- W2061082364 title "Structure and bonding in late transition metal dinuclear complexes with local trigonal planar geometries" @default.
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- W2061082364 doi "https://doi.org/10.1039/b111680k" @default.
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