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• W2061104509 abstract "The temperature dependence of the proton diffusion constant, DH+, in methanol-doped ice was studied over the wide temperature range of 80−260 K. For that purpose, we measured the time-resolved fluorescence of a flavin mononucleotide (FMN) and riboflavin in ice doped with HCl or HF. The analysis of the fluorescence quenching provided the value of DH+. We found that the temperature dependence of DH+ at T > 235 K is rather small, whereas at T < 235 K, it is rather large. These temperature-dependence results are similar to previous conductivity measurements. We used a stepwise, two-coordinate qualitative proton transfer model to explain the temperature dependence of DH+ in ice." @default.
• W2061104509 created "2016-06-24" @default.
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• W2061104509 date "2009-05-18" @default.
• W2061104509 modified "2023-10-04" @default.
• W2061104509 title "Temperature Dependence of Proton Diffusion in I_h Ice" @default.
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• W2061104509 doi "https://doi.org/10.1021/jp901971q" @default.
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