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- W2061110354 abstract "Abstract Well-defined poly(alkylene trimethylsilylphosphite)s (P + 3) were obtained for the first time via silylation of poly(oxyethylene H-phosphonate)s (P + 5) with N,O-bis(trimethylsilyl)acetamide or trimethylsilyl chloride. The reaction with both silylating agents proceeds at room temperature in quantitative conversion. It has been followed by 1 H and 31 P NMR spectroscopy. Poly(alkylene trimethylsilylphosphite)s represent important precursors for the preparation of polymeric aminophosphonic acids, α-hydroxyphosphonates, as well as in a Staudinger-polyphosphite reaction with azides yielding polyphosphoramides." @default.
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- W2061110354 date "2015-01-01" @default.
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- W2061110354 title "Sylilation of poly(alkylene H-phosphonate)s – Rapid and efficient method for obtaining poly(alkylene trisilylmethylphosphite)s" @default.
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- W2061110354 doi "https://doi.org/10.1016/j.eurpolymj.2014.11.010" @default.
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