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• W2061127737 abstract "Well-defined 25 nm nickel phosphide nanoparticles act as a colloidal catalyst for the chemoselective hydrogenation of terminal and internal alkynes. Cis-alkenes are obtained in mild conditions with good conversion and selectivity. The phosphorus inserted in the Ni–P nanoparticles is critical for the selectivity of the nanocatalyst. Mechanistic investigations using isotope labeling provide insight on the reactants interaction with the nanoparticles surface. They pinpoint the occurrence of CH bond cleavage in terminal alkynes during the reaction." @default.
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• W2061127737 date "2012-02-01" @default.
• W2061127737 modified "2023-10-17" @default.
• W2061127737 title "Nickel phosphide nanocatalysts for the chemoselective hydrogenation of alkynes" @default.
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• W2061127737 doi "https://doi.org/10.1016/j.nantod.2011.12.003" @default.
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