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- W2061135550 abstract "Convenient one-pot reduction-complexation reactions of hexachloroplatinato(IV) anions to (η4-alkadiene)dichloroplatinum(II) complexes (η4-alkadiene = COD, DAE, DCPD, NBD) under suitable phase-transfer catalysis conditions are reported. Reduction to zerovalent platinum alkene complexes has been obtained in the presence of an excess of alkene, potassium formate and 18-crown-6 as phase-transfer catalyst (alkene = COD, NB, dba). The crystal and molecular structure of [Pt1.03(dba)3]·CH2Cl2 has been studied by X-ray diffraction methods: it can be described as a solid solution of Pt(dba)3 and Pt2(dba)3, the mononuclear complex being largely prevailing." @default.
- W2061135550 created "2016-06-24" @default.
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- W2061135550 date "2011-04-01" @default.
- W2061135550 modified "2023-10-16" @default.
- W2061135550 title "Convenient preparation of (η4-alkadiene)dichloroplatinum(II) complexes from [PtCl6]2− anions and their reduction to platinum(0) alkene complexes under phase-transfer catalysis conditions" @default.
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- W2061135550 doi "https://doi.org/10.1016/j.jorganchem.2010.12.043" @default.
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