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• W2061158049 endingPage "2000" @default.
• W2061158049 startingPage "1983" @default.
• W2061158049 abstract "The title materials display anomalous electrical, magnetic and optical properties. They have the characteristics of Mott insulators showing high electrical resistance and ligand-field optical spectra, but at the same time they adopt a magnetic ground state which is neither of Curie-Weiss type nor indeed of some standard antiferromagnetically ordered condition. The observed state is one of lowish, isotropic, and almost temperature-independent paramagnetism. The authors have studied the magnetic properties of Sc-doped TiOX, seeking possible indications of the existence of the resonant valence bond or RVB state-the state currently suggested by some to be responsible for high-temperature superconductivity in the mixed-valence cuprates. It is necessary to distinguish between RVB and some extreme case of magnetic frustration in these S=1/2, 2D oxyhalide systems. The authors' tentative conclusion is that TiOX presents an RVB ground state which Sc doping renders glassy and static." @default.
• W2061158049 created "2016-06-24" @default.
• W2061158049 creator A5030293123 @default.
• W2061158049 creator A5066541875 @default.
• W2061158049 date "1993-03-29" @default.
• W2061158049 modified "2023-10-09" @default.
• W2061158049 title "TiOCl, TiOBr-are these RVB d¹, S=1/2 materials? The results of scandium substitution set in the context of other S=1/2 systems of current interest for high-temperature superconductivity and the metal-insulator transition" @default.
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