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- W2061165348 abstract "The unusual and unique ability of O2 as target gas in kV collision-induced dissociations, to enhance a specific fragmentation of a mass selected ion, has been examined in detail. The affected dissociations studied were the loss of CH3* from CH3CH+X (X = OH, CH3, NH2, SH); CH3* and C1* loss from CH3C+(C1)CH3; C2H5* loss from CH3CH2CH+X (X = OH and NH2); H* loss from +CH2OH and +CH2NH2; O loss from 1,2-, 1,3-, and 1,4-C6H4(NO2)2+*; CH3NO+*; C6HsNO2+*; C5H5NO+* (pyridine N-oxide); 3- and 4-CH3C5H4NO+*. A general explanation of the phenomena, which was semiquantitatively tested in the present work, can be summarized as follows: the ion - O2 encounter excites the target molecules to their 3sigma(g)- state which resonantly return this energy to electronic state(s) in the ion. The excited ion now contains a sharp excess of a narrow range of internal energies, thus significantly and only enhancing fragmentations whose activation energies lie within this small energy manifold." @default.
- W2061165348 created "2016-06-24" @default.
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- W2061165348 date "2001-01-01" @default.
- W2061165348 modified "2023-10-10" @default.
- W2061165348 title "The behavior of oxygen as a collision-induced dissociation target gas" @default.
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- W2061165348 doi "https://doi.org/10.1016/s1044-0305(00)00201-4" @default.
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