Matches in SemOpenAlex for { <https://semopenalex.org/work/W2061172904> ?p ?o ?g. }
Showing items 1 to 91 of
91
with 100 items per page.
- W2061172904 endingPage "1174" @default.
- W2061172904 startingPage "1171" @default.
- W2061172904 abstract "We have discovered the ability of 129Xe NMR spectroscopy to discriminate between the xenon complexes of cryptophane-A 1 and its deuterated congeners 2−6 in solution. At 238 K, under slow exchange conditions, the upfield shift experienced by the xenon atom upon complexation by 1 (190 ppm) is increased (up to ∼0.6%) when the hosts are deuterated. By using mixtures of deuterated and nondeuterated hosts, such as 1 and 6, the dynamics of a xenon atom can thus be traced between three different sites (one free and two bound states). We have demonstrated that some of the dynamic features of the exchange between these sites can be extracted from 2D-EXSY experiments, using a suitable kinetic model. We conclude that the exchange of a xenon atom between different hosts occurs by travelling through the solution rather than upon collision of two hosts." @default.
- W2061172904 created "2016-06-24" @default.
- W2061172904 creator A5009184980 @default.
- W2061172904 creator A5023874849 @default.
- W2061172904 creator A5077734239 @default.
- W2061172904 creator A5089720079 @default.
- W2061172904 date "2000-01-29" @default.
- W2061172904 modified "2023-10-16" @default.
- W2061172904 title "<sup>129</sup>Xe NMR Spectroscopy of Deuterium-Labeled Cryptophane-A Xenon Complexes: Investigation of Host−Guest Complexation Dynamics" @default.
- W2061172904 cites W1988070049 @default.
- W2061172904 cites W1993893925 @default.
- W2061172904 cites W2005728717 @default.
- W2061172904 cites W2029482450 @default.
- W2061172904 cites W2034637985 @default.
- W2061172904 cites W2036260351 @default.
- W2061172904 cites W2074770586 @default.
- W2061172904 cites W2079806014 @default.
- W2061172904 cites W4252228692 @default.
- W2061172904 doi "https://doi.org/10.1021/ja993053t" @default.
- W2061172904 hasPublicationYear "2000" @default.
- W2061172904 type Work @default.
- W2061172904 sameAs 2061172904 @default.
- W2061172904 citedByCount "87" @default.
- W2061172904 countsByYear W20611729042012 @default.
- W2061172904 countsByYear W20611729042015 @default.
- W2061172904 countsByYear W20611729042016 @default.
- W2061172904 countsByYear W20611729042017 @default.
- W2061172904 countsByYear W20611729042018 @default.
- W2061172904 countsByYear W20611729042019 @default.
- W2061172904 countsByYear W20611729042020 @default.
- W2061172904 countsByYear W20611729042021 @default.
- W2061172904 countsByYear W20611729042022 @default.
- W2061172904 countsByYear W20611729042023 @default.
- W2061172904 crossrefType "journal-article" @default.
- W2061172904 hasAuthorship W2061172904A5009184980 @default.
- W2061172904 hasAuthorship W2061172904A5023874849 @default.
- W2061172904 hasAuthorship W2061172904A5077734239 @default.
- W2061172904 hasAuthorship W2061172904A5089720079 @default.
- W2061172904 hasConcept C121332964 @default.
- W2061172904 hasConcept C147789679 @default.
- W2061172904 hasConcept C149635348 @default.
- W2061172904 hasConcept C178790620 @default.
- W2061172904 hasConcept C184779094 @default.
- W2061172904 hasConcept C185592680 @default.
- W2061172904 hasConcept C32891209 @default.
- W2061172904 hasConcept C41008148 @default.
- W2061172904 hasConcept C548442186 @default.
- W2061172904 hasConcept C58312451 @default.
- W2061172904 hasConcept C58364064 @default.
- W2061172904 hasConcept C62520636 @default.
- W2061172904 hasConcept C66974803 @default.
- W2061172904 hasConcept C71240020 @default.
- W2061172904 hasConcept C8010536 @default.
- W2061172904 hasConcept C93738149 @default.
- W2061172904 hasConceptScore W2061172904C121332964 @default.
- W2061172904 hasConceptScore W2061172904C147789679 @default.
- W2061172904 hasConceptScore W2061172904C149635348 @default.
- W2061172904 hasConceptScore W2061172904C178790620 @default.
- W2061172904 hasConceptScore W2061172904C184779094 @default.
- W2061172904 hasConceptScore W2061172904C185592680 @default.
- W2061172904 hasConceptScore W2061172904C32891209 @default.
- W2061172904 hasConceptScore W2061172904C41008148 @default.
- W2061172904 hasConceptScore W2061172904C548442186 @default.
- W2061172904 hasConceptScore W2061172904C58312451 @default.
- W2061172904 hasConceptScore W2061172904C58364064 @default.
- W2061172904 hasConceptScore W2061172904C62520636 @default.
- W2061172904 hasConceptScore W2061172904C66974803 @default.
- W2061172904 hasConceptScore W2061172904C71240020 @default.
- W2061172904 hasConceptScore W2061172904C8010536 @default.
- W2061172904 hasConceptScore W2061172904C93738149 @default.
- W2061172904 hasIssue "6" @default.
- W2061172904 hasLocation W20611729041 @default.
- W2061172904 hasOpenAccess W2061172904 @default.
- W2061172904 hasPrimaryLocation W20611729041 @default.
- W2061172904 hasRelatedWork W1990468368 @default.
- W2061172904 hasRelatedWork W2002402576 @default.
- W2061172904 hasRelatedWork W2033372850 @default.
- W2061172904 hasRelatedWork W2038959075 @default.
- W2061172904 hasRelatedWork W2046444400 @default.
- W2061172904 hasRelatedWork W204694417 @default.
- W2061172904 hasRelatedWork W2092550594 @default.
- W2061172904 hasRelatedWork W2371213232 @default.
- W2061172904 hasRelatedWork W78105443 @default.
- W2061172904 hasRelatedWork W2183623085 @default.
- W2061172904 hasVolume "122" @default.
- W2061172904 isParatext "false" @default.
- W2061172904 isRetracted "false" @default.
- W2061172904 magId "2061172904" @default.
- W2061172904 workType "article" @default.