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- W2061174639 abstract "Styrene-butyl acrylate-acrylic acid latex submonolayers prepared using a non-reactive phosphate surfactant together with a reactive sulfonate surfactant were examined in a transmission microscope using electron energy loss spectroscopy imaging (ESI-TEM). Phosphorus is nearly absent from the particles core but it is detected in a thick shell and in unusual, strongly scattering structures with a low carbon content, and largely made out of inorganic phosphate. P is also dispersed outside the particles, while S is uniformly distributed within then. The Na and N elemental maps show that the respective monovalent ions (Na+ and NH4+) have different distributions, in the latex: Na signal within the particles is stronger than in the background, while N is accumulated at the particle borders. The distributions of surfactant and counter-ions are thus different from some current assumptions, but they support recent results on the distribution of ionic constituents in latex films, by scanning electric potential microscopy." @default.
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- W2061174639 date "2004-02-01" @default.
- W2061174639 modified "2023-10-16" @default.
- W2061174639 title "Surfactant and counter-ion distribution in styrene-butyl acrylate-acrylic acid dry latex submonolayers" @default.
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- W2061174639 doi "https://doi.org/10.1590/s0103-50532004000100012" @default.
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