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- W2061188595 abstract "Selenium and bromine were refluxed in methanol and stirred with ethylenethiourea to give yellow crystals of [(Se-ettu)2]Br2 (ettu = ethylenethiourea). The first reported 1,2-diselenonium dication stabilized by sulfur atoms is air unstable and yields a three-dimensional lattice with Se+···Br−···Se+ bridges enclosing also single Se+···Br− interactions and H···Br− bonds. The air instability of [(Se-ettu)2]Br2 probably is due to redox reactions which lead to the decomposition of ethylenethiourea with precipitation of sulfur." @default.
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- W2061188595 date "2008-03-01" @default.
- W2061188595 modified "2023-10-05" @default.
- W2061188595 title "Synthesis and Structural Features of a New Diselenonium Dication Stabilized by Sulfur Atoms of Thiourea Groups: X-ray Characterization of [(Se-ettu)2]Br2 (ettu = ethylenethiourea)" @default.
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- W2061188595 doi "https://doi.org/10.1002/zaac.200700491" @default.
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