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• W2061196324 abstract "Abstract The depolarization behaviour of iodine-doped polycarbonate (PC) films was studied as a function of iodine (I 2 ) concentrations varying from 0.02 to 0.3 g (100 cm 3 ) −1 of 2.5% PC solution in dichloromethane. Polarized PC:I 2 films exhibit three thermally stimulated depolarization current peaks, designated peaks I, II and III, in the temperature regions 340–350 K, 407–415 K and 455–482 K, with activation energies of 0.43–0.51, 0.69–0.75 and 1.20–1.47 eV respectively. The decrease in the magnitude of peak I and its shift towards lower temperatures has been explained on the basis of the formation of charge transfer complexes with the polymer chain by the interstitially placed iodine; this reduces the interaction between the polar molecules, and their electrostatic field may possibly act in a direction opposite to the direction of the polarizing field. These conclusions regarding charge transfer complex formation have been confirmed by visible and IR optical absorption data on pure and iodine-doped PC films. The slight decrease in the magnitude of peak II is attributed to the destruction or neutralization of some of the trapping sites on doping with iodine impurities. Peak III was associated with the asymmetrical distribution of the ionic charge carriers formed during the growth of thin films." @default.
• W2061196324 created "2016-06-24" @default.
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• W2061196324 date "1981-04-01" @default.
• W2061196324 modified "2023-10-02" @default.
• W2061196324 title "The effect of doping on the dielectric relaxations of polycarbonate thin films" @default.
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• W2061196324 doi "https://doi.org/10.1016/0040-6090(89)90591-9" @default.
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