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• W2061199001 abstract "Abstract The tittle compound has been prepared and characterized spectroscopically and by single-crystal X-ray crystallography (refined to R1 = 0.052, Rw = 0.064 with 1837 data having I > 3σ(I)). The dithioacetylacetonate (SacSac) methyl groups are NMR equivalent at room temperature, but can be resolved at temperatures below 288 K. The compound crystallizes in the monoclinic space group P21/n with a = 7.6107(3) A, b = 18.1466(28) A and c = 11.5270(5) A; β =98.459(3)°, V = 1574.12(25) A3, and Z = 4. The coordination about the nickel(II) is planar. Important nickelligand lengths are NiS (trans Cl) 2.108(2) A, NiS (trans P) 2.154(2) A, NiCl 2.206(2) A, NiP 2.232(2) A with angles SNiS 97.9(1)°, SNiCl 85.Cl 85.6(1)°, SNiP 91.4(1)° and ClNiP 85.2(1)°. Two of the triethylphosphine ethyl groups lie in a plane approximately normal to the rest of the molecule. The dithioacetylacetonate dimensions are similar to those in Ni(SacSac)2, although the chelate bite is smaller, and there may be some asymmetry in the CS bonding in Ni(SacSac)PEt3Cl. The molecules pack with their chelate rings approximately parallel." @default.
• W2061199001 created "2016-06-24" @default.
• W2061199001 creator A5010322152 @default.
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• W2061199001 date "1980-01-01" @default.
• W2061199001 modified "2023-09-27" @default.
• W2061199001 title "Sulphur chelates 33. Preparation, characterization and x-ray structure determination of (chloro)(pentane-2,4-dithionato)(triethylphosphine)nickel(II), Ni(SacSac)(PEt3)Cl, an asymmetric complex which displays fluxional behavior in solution on the NMR time scale" @default.
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• W2061199001 doi "https://doi.org/10.1016/s0020-1693(00)93643-0" @default.
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