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• W2061234880 abstract "Abstract We report the Fourier transform microwave spectra of four isotopologues of the hetero triad pyridine–Ar–Ne, formed by the combination of two isotopes of the nitrogen atom ( 14 N and 15 N) in pyridine with two isotopes of the rare gas (RG) atoms ( 20 Ne and 22 Ne), by using pulsed jet spectroscopy. We detected the conformer denoted [1,1], with the Ne and Ar atoms located one on each side of the ring plane. The [2,0] species, with the two RG atoms on the same side of the ring, was not observed. Ab initio MP2/6‐311++G** calculations suggest the rotational spectrum of this species to be complicated by the presence of several almost equivalent minima, separated by very low barriers. Four structural van der Waals parameters, R Ar , R Ne , θ Ar and θ Ne , which localize the RG atoms with respect to pyridine, are determined. The 14 N nuclear quadrupole coupling constants are obtained for the isotopologues containing this nucleus." @default.
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• W2061234880 date "2009-09-28" @default.
• W2061234880 modified "2023-09-30" @default.
• W2061234880 title "Rotational Spectrum of the Mixed van der Waals Triad Pyridine-Ar-Ne" @default.
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• W2061234880 doi "https://doi.org/10.1002/cphc.200900366" @default.
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