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- W2061258780 abstract "In the FeIII-FeV manifold the formation of the iron-carbon bond was found to be very fast, but the evolution to give ketone was slow at −20 °C and −40 °C. However, the efficiency at the latter temperature was good. The iron-carbon bond can be captured rapidly by I− or by PhSeH. We have confirmed that either way to measure the iron-carbon bond gives essentially the same results. In contrast to the FeIII-FeV manifold the reactions at −20 °C in the FeII-FeIV manifold are very fast for both iron-carbon bond formation and evolution to final products. In this manifold the reactions at −20 °C are more efficient than those at −5 °C." @default.
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- W2061258780 date "1998-12-01" @default.
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- W2061258780 title "The selective functionalization of saturated hydrocarbons. Part 45. The effect of lower temperature on the rate and efficiency of formation of oxidized products in the FeIII-FeV and FeII-FeIV manifolds" @default.
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- W2061258780 doi "https://doi.org/10.1016/s0040-4020(98)00907-7" @default.
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