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• W2061261051 abstract "The temperature dependence of the 1H NMR spin-lattice relaxation time T1 has been measured for solid chloropentamethylbenzene in the range 90–380 K. A single T1 minimum of 36.5 ms was observed around 278 K at the Larmor frequency of 18 MHz and has been assigned to in-plane molecular reorientation about the pseudohexad C′6 axis over the nonequivalent potential wells. With the aid of the reported X-ray analyses, the results have been analyzed by employing the method developed by Anderson. The activation energy has been evaluated as 27 kJ mol−1 which amounts to nearly the same value as hexamethylbenzene. A gradual decrease of T1 below 150 K was attributed to the methyl groups rotation about their C3 axes over the barriers of 3.0 kJ mol−1." @default.
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• W2061261051 date "1997-04-01" @default.
• W2061261051 modified "2023-09-27" @default.
• W2061261051 title "A 1H NMR study of molecular motions in chloropentamethylbenzene" @default.
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• W2061261051 doi "https://doi.org/10.1016/s0022-2860(96)09606-8" @default.
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