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- W2061264601 abstract "A new ternary phase W5As2.5P1.5has been synthesized and investigated by means of X-ray powder diffraction. The tetragonal unit cell dimensions area=9.4729 (3) Å andc=3.2414 (2) Å (space groupI4/mwithZ=2). The crystal structure has been refined by the Rietveld method using the structure Mo5As4(Ti5Te4-type) as a related model (RF=0.030 andRP=0.116 for 160 reflections and 30 refined parameters). In the structure, the metalloid sublattice (As, P) is wholly disordered and there is no interaction between the metalloid atoms, while W–W bonding leads to the formation of octahedral W6clusters inserted inX8cubes (X=As, P). The significant aspect of this structure consists of the condensation of these W6X8units through two opposite tungsten atoms. This results in the formation of one-dimensional columns with the composition W4W2/2X8/2(W5X4) parallel to thec-axis of the unit cell. Such a condensation of octahedral W6clusters has never been observed in solid state chemistry, the only examples of octahedral W6clusters being found in halide and chalcogenide chemistry but as isolated units. A general survey on Ti5Te4or derivative-type structure compounds is also given." @default.
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- W2061264601 date "1997-07-01" @default.
- W2061264601 modified "2023-10-16" @default.
- W2061264601 title "W5As2.5P1.5: The First One-Dimensional Vertex-Linked W6Cluster" @default.
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- W2061264601 doi "https://doi.org/10.1006/jssc.1997.7386" @default.
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