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- W2061289904 abstract "Several new heteropoly compounds catalysts with pronounced activities in NO x conversion via adsorption-decomposition process in a fixed-bed reactor were evaluated concerning the principal internal and external factors having marked effects on the process of adsorption. Results showed that substitution of H + in HPW (H 3 PW 12 O 40 •6H 2 O) by NH 4 + results in marked enhancement of the catalyst activity, however, substitution of coordination atom W in the [PW 12 O 40 ] 3- anion by one or more Mo atoms tends to lower the catalyst activity and such tendency deepens with the increase in the Mo atom numbers introduced. It is for the first time that the nano-effect was observed with nano (NH 4 ) 3 PW 12 O 40 catalyst, in which a 1.6% to 10.6% enhancement in NO x adsorption efficiency was obtained in comparison with the same catalyst in normal particle size. By IR analysis, NO was found to be adsorbed via interaction with the proton of HPW structure. With the aid of GC-MS analysis, the process effectiveness for NO x decomposition into N 2 was confirmed." @default.
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- W2061289904 date "2011-05-01" @default.
- W2061289904 modified "2023-09-27" @default.
- W2061289904 title "Solid P-W Keggin Heteropoly Compounds as Effective Catalysts for the Sorption-Decomposition of NO<sub>X</sub>" @default.
- W2061289904 doi "https://doi.org/10.4028/www.scientific.net/amr.233-235.355" @default.
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