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• W2061292051 abstract "Abstract A series of palladium complexes of the type [Pd( ph PS 2 )(PAr 3 )] ( ph PS 2 ) = [PhP(C 6 H 4 -2-S) 2 ] 2− have been synthesized in good yields and their crystal structures determined. Heck coupling reactions were carried out using the [Pd( ph PS 2 )(PPh 3 )] ( 1 ), [Pd( ph PS 2 ){P(C 6 H 4 -4-Cl) 3 }] ( 2 ), [Pd( ph PS 2 ){P(C 6 H 4 -4-F) 3 }] ( 3 ), [Pd( ph PS 2 ){P(C 6 H 4 -4-CF 3 ) 3 }] ( 4 ), [Pd( ph PS 2 ){P(C 6 H 4 -4-Me) 3 }] ( 5 ) and [Pd( ph PS 2 ){P(C 6 H 4 -4-OMe) 3 }] ( 6 ) complexes as catalyst precursors in order to examine the potential effect of the para -substituted triarylphosphines in the reaction of bromobenzene and styrene." @default.
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• W2061292051 date "2007-04-01" @default.
• W2061292051 modified "2023-10-17" @default.
• W2061292051 title "Synthesis, characterization and catalytic evaluation in the Heck coupling reactions of S–P–S pincer complexes of the type [Pd{PhP(C6H4-2-S)2}(PAr3)]" @default.
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• W2061292051 doi "https://doi.org/10.1016/j.ica.2006.10.029" @default.
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