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- W2061323450 abstract "The isomeric 7-t-butylbicyclo[2.2.1]hept-2-en-7-ols afford isomeric dienes (7-methyl-7-(2′-propenyl)-bicyclo[2.2.1]hept-2-enes) by Wagner–Meerwein rearrangement on treatment with thionyl bromide or acid. Methyl migration in the nonclassical 7-t-butylbicyclo[2.2.1]hept-2-en-7-yl cation intermediate occurs with a substantial syn preference, in sharp contrast to the anti preference exhibited in capture of similar cations by external nucleophiles. The result is interpreted in terms of a steric factor." @default.
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- W2061323450 date "1973-12-15" @default.
- W2061323450 modified "2023-09-25" @default.
- W2061323450 title "Carbonium Ion Rearrangement with Retention at the Migration Terminus" @default.
- W2061323450 doi "https://doi.org/10.1139/v73-611" @default.
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