Matches in SemOpenAlex for { <https://semopenalex.org/work/W2061350765> ?p ?o ?g. }
- W2061350765 endingPage "7142" @default.
- W2061350765 startingPage "7135" @default.
- W2061350765 abstract "Polarization deficiency and excess ion hydration free energy at an electric field E (ion hydration free energy at the field E subtracted by the ion hydration free energy at zero field) of hydrated calcium, sodium, and chloride ions have been determined by Monte Carlo simulations. A spherical cell containing either one ion and molecular water or only molecular water subjected to an external electrical field was used. The permittivity of pure water decreases as E is increased, in quantitative agreement with previous simulation studies and the Booth theory. The excess ion hydration free energy depends quadratically on E up to ca. 2.5·108 V/m, whereas it becomes linear in E at higher field due to dielectric saturation. The values of the excess ion hydration free energies are in quantitative agreement with measured dependencies of the relative permittivity of electrolyte solution upon the ion concentration. A primitive polarization model of electrolyte solution near charged interfaces is proposed. The use of this model leads to an additional effective repulsive force acting on hydrated ions near charged surfaces and significantly affects the distribution of calcium ions near such surfaces." @default.
- W2061350765 created "2016-06-24" @default.
- W2061350765 creator A5048102843 @default.
- W2061350765 creator A5048576171 @default.
- W2061350765 date "2003-06-27" @default.
- W2061350765 modified "2023-10-16" @default.
- W2061350765 title "Polarization Deficiency and Excess Free Energy of Ion Hydration in Electric Fields" @default.
- W2061350765 cites W1504164119 @default.
- W2061350765 cites W1965409637 @default.
- W2061350765 cites W1968516567 @default.
- W2061350765 cites W1969403712 @default.
- W2061350765 cites W1970827957 @default.
- W2061350765 cites W1972326506 @default.
- W2061350765 cites W1973287722 @default.
- W2061350765 cites W1975510301 @default.
- W2061350765 cites W1980958035 @default.
- W2061350765 cites W1982200982 @default.
- W2061350765 cites W1985878326 @default.
- W2061350765 cites W1989613186 @default.
- W2061350765 cites W1991871928 @default.
- W2061350765 cites W199380026 @default.
- W2061350765 cites W1995658925 @default.
- W2061350765 cites W1995968473 @default.
- W2061350765 cites W1996617052 @default.
- W2061350765 cites W1997265863 @default.
- W2061350765 cites W2002236155 @default.
- W2061350765 cites W2006284495 @default.
- W2061350765 cites W2007935247 @default.
- W2061350765 cites W2015026641 @default.
- W2061350765 cites W2016222422 @default.
- W2061350765 cites W2016540952 @default.
- W2061350765 cites W2018971972 @default.
- W2061350765 cites W2022051913 @default.
- W2061350765 cites W2028590095 @default.
- W2061350765 cites W2029980830 @default.
- W2061350765 cites W2040295094 @default.
- W2061350765 cites W2040816544 @default.
- W2061350765 cites W2041248383 @default.
- W2061350765 cites W2042285588 @default.
- W2061350765 cites W2043291960 @default.
- W2061350765 cites W2046758026 @default.
- W2061350765 cites W2047915378 @default.
- W2061350765 cites W2049475242 @default.
- W2061350765 cites W2050973323 @default.
- W2061350765 cites W2051328123 @default.
- W2061350765 cites W2052737939 @default.
- W2061350765 cites W2054967121 @default.
- W2061350765 cites W2055638793 @default.
- W2061350765 cites W2055945884 @default.
- W2061350765 cites W2057402549 @default.
- W2061350765 cites W2061905772 @default.
- W2061350765 cites W2062979427 @default.
- W2061350765 cites W2068113560 @default.
- W2061350765 cites W2073275733 @default.
- W2061350765 cites W2075662564 @default.
- W2061350765 cites W2078762277 @default.
- W2061350765 cites W2079179785 @default.
- W2061350765 cites W2079530884 @default.
- W2061350765 cites W2079783620 @default.
- W2061350765 cites W2083140740 @default.
- W2061350765 cites W2086630515 @default.
- W2061350765 cites W2088133397 @default.
- W2061350765 cites W2093128638 @default.
- W2061350765 cites W2115377038 @default.
- W2061350765 cites W2135964386 @default.
- W2061350765 cites W2143879809 @default.
- W2061350765 cites W2149310953 @default.
- W2061350765 cites W2167885171 @default.
- W2061350765 cites W2316176511 @default.
- W2061350765 cites W2337120805 @default.
- W2061350765 cites W2597545515 @default.
- W2061350765 cites W3100406469 @default.
- W2061350765 cites W4230257048 @default.
- W2061350765 doi "https://doi.org/10.1021/jp030035w" @default.
- W2061350765 hasPublicationYear "2003" @default.
- W2061350765 type Work @default.
- W2061350765 sameAs 2061350765 @default.
- W2061350765 citedByCount "23" @default.
- W2061350765 countsByYear W20613507652012 @default.
- W2061350765 countsByYear W20613507652013 @default.
- W2061350765 countsByYear W20613507652015 @default.
- W2061350765 countsByYear W20613507652016 @default.
- W2061350765 countsByYear W20613507652017 @default.
- W2061350765 countsByYear W20613507652018 @default.
- W2061350765 countsByYear W20613507652022 @default.
- W2061350765 crossrefType "journal-article" @default.
- W2061350765 hasAuthorship W2061350765A5048102843 @default.
- W2061350765 hasAuthorship W2061350765A5048576171 @default.
- W2061350765 hasConcept C113196181 @default.
- W2061350765 hasConcept C114614502 @default.
- W2061350765 hasConcept C121332964 @default.
- W2061350765 hasConcept C133386390 @default.
- W2061350765 hasConcept C145148216 @default.
- W2061350765 hasConcept C147789679 @default.
- W2061350765 hasConcept C148093993 @default.
- W2061350765 hasConcept C159467904 @default.
- W2061350765 hasConcept C168651791 @default.
- W2061350765 hasConcept C17525397 @default.