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- W2061361603 abstract "An algebraic formalism allows one to transform freely between complementary zero-order local and normal representations of vibrational dynamics of ABA triatomics. A semiclassical Interpretation of the local mode representation recovers the picture of Sibert et al. of an effective rotating top hindered by a double-well barrier. The complementary, but previously elusive normal representation pictures the vibrations as a top in an effective magnetic field. Darling—Dennison normal mode coupling due to off-diagonal unharmonic effects is represented by a quadruple-well barrier. In this normal representation, states with normal character are above the dynamical barrier, and states with local character are trapped." @default.
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- W2061361603 title "Vibrational dynamics of ABA triatomics in a semiclassical algebraic approach" @default.
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