FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2061380636> ?p ?o ?g. }

• W2061380636 endingPage "2804" @default.
• W2061380636 startingPage "2804" @default.
• W2061380636 abstract "New examples of nitrogen base adducts of dinuclear Co(II), Ni(II) and Cu(II) complexes of the doubly deprotonated forms of 1,3-aryl linked bis-beta-diketones of type [RC(=O)CH(2)C(=O)C(6)H(4)C(=O)CH(2)C(=O)R] (L(1)H(2)) incorporating the mono- and difunctional amine bases pyridine (Py), 4-ethylpyridine (EtPy), piperidine (pipi), 1,4-piperazine (pip), N-methylmorpholine (mmorph), 1,4-dimethylpiperazine (dmpip) and N,N,N',N'-tetramethylethylenediamine (tmen) have been synthesised by reaction of the previously reported [Cu(2)(L(1))(2)].2.5THF (R = Me), [Cu(2)(L(1))(2)(THF)(2)] (R = t-Bu), [Ni(2)(L(1))(2)(Py)(4)] (R = t-Bu) and [Co(2)(L(1))(2)(Py)(4)] (R = t-Bu) complexes with individual bases of the above type. Comparative X-ray structural studies involving all ten base adduct derivatives have been obtained and reveal a range of interesting discrete and polymeric molecular architectures. The respective products have the following stoichiometries: [Cu(2)(L(1))(2)(Py)(2)].Py (R = Me), [Cu(2)(L(1))(2)(EtPy)(2)].2EtPy (R = t-Bu), [Cu(2)(L(1))(2)(pipi)(2)].2pipi (R = t-Bu), [Cu(2)(L(1))(2)(mmorph)(2)] (R = t-Bu), [Cu(2)(L(1))(2)(tmen)(2)] (R = t-Bu) and {[Cu(2)(L(1))(2)(pip)].pip.2THF}(n), [Co(2)(L(1))(2)(tmen)(2)] (R = t-Bu), [Ni(2)(L(1))(2)(Py)(4)].dmpip (R = t-Bu), [Ni(2)(L(1))(2)(pipi)(4)].pipi (R = t-Bu) and [Ni(2)(L(1))(2)(tmen)(2)] (R = t-Bu). The effect of pressure on the X-ray structure of [Cu(2)(L(1))(2)(mmorph)(2)] has been investigated. An increase in pressure from ambient to 9.1 kbar resulted in modest changes to the unit cell parameters as well as a corresponding decrease of 6.7 percent in the unit cell volume. While a small 'shearing' motion occurs between adjacent molecular units throughout the lattice, no existing bonds are broken or new bonds formed." @default.
• W2061380636 created "2016-06-24" @default.
• W2061380636 creator A5023541806 @default.
• W2061380636 creator A5044709492 @default.
• W2061380636 creator A5047759330 @default.
• W2061380636 creator A5048063917 @default.
• W2061380636 creator A5048957496 @default.
• W2061380636 creator A5056323219 @default.
• W2061380636 creator A5072217514 @default.
• W2061380636 creator A5073308134 @default.
• W2061380636 creator A5073361343 @default.
• W2061380636 creator A5083576143 @default.
• W2061380636 creator A5091125670 @default.
• W2061380636 date "2010-01-01" @default.
• W2061380636 modified "2023-09-27" @default.
• W2061380636 title "New discrete and polymeric supramolecular architectures derived from dinuclear Co(ii), Ni(ii) and Cu(ii) complexes of aryl-linked bis-β-diketonato ligands and nitrogen bases: synthetic, structural and high pressure studies" @default.
• W2061380636 cites W1512319944 @default.
• W2061380636 cites W1909419175 @default.
• W2061380636 cites W1925495285 @default.
• W2061380636 cites W1964785717 @default.
• W2061380636 cites W1965861810 @default.
• W2061380636 cites W1969635440 @default.
• W2061380636 cites W1969749365 @default.
• W2061380636 cites W1970577948 @default.
• W2061380636 cites W1971087837 @default.
• W2061380636 cites W1973800116 @default.
• W2061380636 cites W1975256305 @default.
• W2061380636 cites W1982742193 @default.
• W2061380636 cites W1983423892 @default.
• W2061380636 cites W1987019985 @default.
• W2061380636 cites W1989548381 @default.
• W2061380636 cites W1998897044 @default.
• W2061380636 cites W2001003327 @default.
• W2061380636 cites W2003730249 @default.
• W2061380636 cites W2010789431 @default.
• W2061380636 cites W2012629676 @default.
• W2061380636 cites W2019147939 @default.
• W2061380636 cites W2019661738 @default.
• W2061380636 cites W2034456898 @default.
• W2061380636 cites W2040655424 @default.
• W2061380636 cites W2044828144 @default.
• W2061380636 cites W2047010149 @default.
• W2061380636 cites W2047553501 @default.
• W2061380636 cites W2050112821 @default.
• W2061380636 cites W2052156219 @default.
• W2061380636 cites W2052410207 @default.
• W2061380636 cites W2061246513 @default.
• W2061380636 cites W2063334178 @default.
• W2061380636 cites W2063393806 @default.
• W2061380636 cites W2067416688 @default.
• W2061380636 cites W2069681423 @default.
• W2061380636 cites W2075515689 @default.
• W2061380636 cites W2084075555 @default.
• W2061380636 cites W2085255516 @default.
• W2061380636 cites W2087212232 @default.
• W2061380636 cites W2087630391 @default.
• W2061380636 cites W2090329827 @default.
• W2061380636 cites W2093977104 @default.
• W2061380636 cites W2094312758 @default.
• W2061380636 cites W2109726134 @default.
• W2061380636 cites W2117000173 @default.
• W2061380636 cites W2119101181 @default.
• W2061380636 cites W2123520040 @default.
• W2061380636 cites W2132950991 @default.
• W2061380636 cites W2133920926 @default.
• W2061380636 cites W2135244721 @default.
• W2061380636 cites W2135865474 @default.
• W2061380636 cites W2136294712 @default.
• W2061380636 cites W2141547271 @default.
• W2061380636 cites W2141820807 @default.
• W2061380636 cites W2143803583 @default.
• W2061380636 cites W2144332006 @default.
• W2061380636 cites W2145214890 @default.
• W2061380636 cites W2152745684 @default.
• W2061380636 cites W2153969400 @default.
• W2061380636 cites W2163638920 @default.
• W2061380636 cites W2168168043 @default.
• W2061380636 cites W2951844653 @default.
• W2061380636 cites W4241058421 @default.
• W2061380636 doi "https://doi.org/10.1039/b920199h" @default.
• W2061380636 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20200706" @default.
• W2061380636 hasPublicationYear "2010" @default.
• W2061380636 type Work @default.
• W2061380636 sameAs 2061380636 @default.
• W2061380636 citedByCount "33" @default.
• W2061380636 countsByYear W20613806362012 @default.
• W2061380636 countsByYear W20613806362013 @default.
• W2061380636 countsByYear W20613806362014 @default.
• W2061380636 countsByYear W20613806362015 @default.
• W2061380636 countsByYear W20613806362016 @default.
• W2061380636 countsByYear W20613806362017 @default.
• W2061380636 countsByYear W20613806362018 @default.
• W2061380636 countsByYear W20613806362019 @default.
• W2061380636 countsByYear W20613806362020 @default.
• W2061380636 countsByYear W20613806362021 @default.
• W2061380636 countsByYear W20613806362023 @default.
• W2061380636 crossrefType "journal-article" @default.
• W2061380636 hasAuthorship W2061380636A5023541806 @default.

• next