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- W2061385779 abstract "The complexes formed by the reactions of nitrosylrutheniurn(III) in hydrochloric acid solutions with tin(II) chloride were investigated. The following reaction products, (Me4N)2[RuCl3(SnCl3)2-NO], [1]; (Me4N)4[RuCl6(SnCl3)2(NO)2]·H2O, [2]; (Me4N)4[RuCl(SnCl3)5], [3] and K3[Ru2-Cl8(H2O)2N], [4] were isolated as crystals and were characterized. On the basis of chemical and thermal analyses, and on the basis of observations of the magnetic properties, the conductivities, and the infrared spectra, it was concluded that complexes [1], [2], and [3] contain terminal or bridging nitrosyl groups and/or a coordinating SnCl3− group, and that complex [4] contains a bridging nitrido group. The presence of the binuclear complex, “K3[Ru2Cl9(NO)2],” which has both the terminal and singly-bridged nitrosyl groups was also suggested. The relations among those complexes were discussed." @default.
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- W2061385779 date "1970-12-01" @default.
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- W2061385779 title "The Ruthenium Complexes Formed by the Reactions of Nitrosylruthenium(III) with Tin(II) in Hydrochloric Acid Solution" @default.
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- W2061385779 doi "https://doi.org/10.1246/bcsj.43.3805" @default.
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