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- W2061416401 abstract "The metabolism of 4‐nitrobiphenyl have been studied in pure cultures of a facultative gram negative strain. The bacterium was able to grow using 4‐nitrobiphenyl as the sole carbon source. The biotransformation products were isolated and identified by combined gas chromatography‐mass spectrometry. Intermediate metabolites of the bio‐transformation cascade were identified as 2,3‐dihydro‐2,3‐dihydroxy‐4'‐nitrobiphenyl, 3,4‐dihydro‐3,4‐dihydroxy‐4'‐nitrobiphenyl,3,4‐dihydroxy‐4'‐nitrobiphenyl,2‐hydroxy‐6‐oxo‐6‐(4'‐nitrophenyl) hexanoic acid and 4‐nitrocinnamic acid. In addition 2 and 4‐hydroxy‐4'‐nitrobiphenyls were detected in the neutral extracts whereas minute amounts of 2‐hydroxy‐3‐nitroso‐4'‐nitrobiphenyl and 4‐amino benzoic acid were also detected. The results from this study indicate that 4‐nitrobiphenyl was degraded to the corresponding nitro‐benzoic acid. The data reported here also suggests that there is a minor metabolic route in the microbial cultures leading to hydroxylated compounds which is similar to those reported in mammalian systems. In addition, we have demonstrated the ability of the bacterium to convert 4‐nitrobiphenyl to the corresponding 2'‐hydroxy‐3'‐nitroso derivative. This unusual reaction is of considerable importance because of the potential toxicity of this metabolite." @default.
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- W2061416401 date "1985-07-01" @default.
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- W2061416401 title "Gas chromatographie‐mass spectrometric characterization of bacterial metabolites of 4‐nitrobiphenyl formed in gram negative strain B‐206†" @default.
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- W2061416401 doi "https://doi.org/10.1080/02772248509357104" @default.
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