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• W2061417811 abstract "Abstract 6 Li- and 15 N-NMR spectroscopic analyses of a labeled chiral bidentate lithium amide ( [ 6 Li , 15 N 2 ]-(R)- 1 ) have shown that it exists as a chelated monomer ( 5 ) in THF and in DME, as a chelated dimer ( 6 ) in toluene and in ether, while as a chelated monomer ( 5 ) in any of these solvents in the presence of 2 equivalents of HMPA. Solvent-dependent enantioselectivities in deprotonation of 4- tert -butylcyclohexanone ( 2 ) by (R)- 1 appear to be correlated to these solution structures." @default.
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• W2061417811 date "1997-05-01" @default.
• W2061417811 modified "2023-10-09" @default.
• W2061417811 title "Stereoselective reactions. 26. Solution structures of chiral bidentate lithium amide in relation to the solvent-dependent enantioselectivities in deprotonation reaction" @default.
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• W2061417811 doi "https://doi.org/10.1016/s0040-4020(97)00422-5" @default.
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