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- W2061418310 abstract "ABA-type triblock copolymers, poly{(γ-benzyl l-aspartate) (BLA)-block-ethylene oxide (EO)-block-BLA}, with a controlled chain length were prepared. The copolymer film (ca. 0.01 mm thickness) was immersed into the water to create a thin, self-sustainable hydrogel membrane (0.01−0.02 mm thickness) that was largely deformable and tough in its equilibrated water-swollen state (water content: 58−83 wt %). Crossed-polarizing microscopy confirmed that the water-swollen membrane had a framework of giant crystalline domains 10 μm−4 mm in size; as far as we know, crystalline domains large enough to observe by an optical microscope in the hydrogels have never been reported. During the water-swelling process, the triblock copolymers showed an α-helix−β-strand transformation of their PBLA blocks and long-range structural formation, which may have reinforced the hydrogel thin membrane, thus increasing its toughness." @default.
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- W2061418310 date "2005-04-30" @default.
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- W2061418310 title "Tough, Thin Hydrogel Membranes with Giant Crystalline Domains Composed of Precisely Synthesized Macromolecules" @default.
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- W2061418310 doi "https://doi.org/10.1021/ma050121p" @default.
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