Matches in SemOpenAlex for { <https://semopenalex.org/work/W2061430101> ?p ?o ?g. }
- W2061430101 endingPage "197" @default.
- W2061430101 startingPage "183" @default.
- W2061430101 abstract "The electron transfer reaction within a donor-acceptor, solvent separated ion pair (2A·+…2D·−) leading to excited singlet, excited triplet, and ground state products is studied within the framework of the theory of nonradiative transitions. Inner sphere as well as outer sphere rearrangement processes are included. The nonadiabatic model presented here predicts an almost linear dependence of lnk upon the free energy change ΔF0 in the abnormal free energy region in contrast to the quadratic dependence predicted by conventional Marcus electron transfer theory. Experimental evidence concerning the quantum yield and kinetics of the chemiluminescent electron transfer reaction between the anion radical and the cation radical of 9,10-diphenylanthracene is presented to demonstrate that the nonadiabatic electron transfer description results in a closer agreement between theory and experiment for the abnormal free energy region than does an adiabatic theory or its generalized version containing a preexponential factor, κ, which might be calculated by a Landau-Zener type formula. However, the present theory still falls short in quantitatively explaining the relatively large observed rates leading to the ground state products, which involve large changes in the free energy ΔF0.It is argued that second order transfer processes involving strongly coupling intermediate states can resolve the remaining discrepancy." @default.
- W2061430101 created "2016-06-24" @default.
- W2061430101 creator A5028151985 @default.
- W2061430101 creator A5050473117 @default.
- W2061430101 date "1974-08-01" @default.
- W2061430101 modified "2023-10-04" @default.
- W2061430101 title "A nonadiabatic description of electron transfer reactions involving large free energy changes" @default.
- W2061430101 cites W1966963999 @default.
- W2061430101 cites W1967298849 @default.
- W2061430101 cites W1969541808 @default.
- W2061430101 cites W1969876717 @default.
- W2061430101 cites W1970625934 @default.
- W2061430101 cites W1971811406 @default.
- W2061430101 cites W1974655343 @default.
- W2061430101 cites W1978275179 @default.
- W2061430101 cites W1981659415 @default.
- W2061430101 cites W1983293350 @default.
- W2061430101 cites W1984265310 @default.
- W2061430101 cites W1987392471 @default.
- W2061430101 cites W1991717832 @default.
- W2061430101 cites W2004306768 @default.
- W2061430101 cites W2007060095 @default.
- W2061430101 cites W2011740529 @default.
- W2061430101 cites W2014739151 @default.
- W2061430101 cites W2028190743 @default.
- W2061430101 cites W2030770255 @default.
- W2061430101 cites W2030862528 @default.
- W2061430101 cites W2032051941 @default.
- W2061430101 cites W2037145543 @default.
- W2061430101 cites W2037592741 @default.
- W2061430101 cites W2047962721 @default.
- W2061430101 cites W2056245889 @default.
- W2061430101 cites W2056807000 @default.
- W2061430101 cites W2061395311 @default.
- W2061430101 cites W2064587301 @default.
- W2061430101 cites W2064905901 @default.
- W2061430101 cites W2075609094 @default.
- W2061430101 cites W2075690719 @default.
- W2061430101 cites W2080601583 @default.
- W2061430101 cites W2081529574 @default.
- W2061430101 cites W2083322996 @default.
- W2061430101 cites W2091237955 @default.
- W2061430101 cites W2092131542 @default.
- W2061430101 cites W2094237409 @default.
- W2061430101 cites W2101448395 @default.
- W2061430101 cites W2111849419 @default.
- W2061430101 cites W2112991393 @default.
- W2061430101 cites W2145773666 @default.
- W2061430101 cites W2161892293 @default.
- W2061430101 cites W2318391977 @default.
- W2061430101 cites W2324714600 @default.
- W2061430101 cites W2334990753 @default.
- W2061430101 doi "https://doi.org/10.1016/0301-0104(74)80017-0" @default.
- W2061430101 hasPublicationYear "1974" @default.
- W2061430101 type Work @default.
- W2061430101 sameAs 2061430101 @default.
- W2061430101 citedByCount "200" @default.
- W2061430101 countsByYear W20614301012012 @default.
- W2061430101 countsByYear W20614301012013 @default.
- W2061430101 countsByYear W20614301012015 @default.
- W2061430101 countsByYear W20614301012016 @default.
- W2061430101 countsByYear W20614301012017 @default.
- W2061430101 countsByYear W20614301012018 @default.
- W2061430101 countsByYear W20614301012019 @default.
- W2061430101 countsByYear W20614301012020 @default.
- W2061430101 countsByYear W20614301012021 @default.
- W2061430101 countsByYear W20614301012022 @default.
- W2061430101 countsByYear W20614301012023 @default.
- W2061430101 crossrefType "journal-article" @default.
- W2061430101 hasAuthorship W2061430101A5028151985 @default.
- W2061430101 hasAuthorship W2061430101A5050473117 @default.
- W2061430101 hasConcept C109663097 @default.
- W2061430101 hasConcept C121332964 @default.
- W2061430101 hasConcept C123669783 @default.
- W2061430101 hasConcept C145148216 @default.
- W2061430101 hasConcept C148898269 @default.
- W2061430101 hasConcept C174256460 @default.
- W2061430101 hasConcept C178790620 @default.
- W2061430101 hasConcept C181500209 @default.
- W2061430101 hasConcept C184779094 @default.
- W2061430101 hasConcept C185592680 @default.
- W2061430101 hasConcept C33062035 @default.
- W2061430101 hasConcept C62520636 @default.
- W2061430101 hasConcept C69523127 @default.
- W2061430101 hasConcept C75473681 @default.
- W2061430101 hasConcept C89169741 @default.
- W2061430101 hasConcept C93391505 @default.
- W2061430101 hasConceptScore W2061430101C109663097 @default.
- W2061430101 hasConceptScore W2061430101C121332964 @default.
- W2061430101 hasConceptScore W2061430101C123669783 @default.
- W2061430101 hasConceptScore W2061430101C145148216 @default.
- W2061430101 hasConceptScore W2061430101C148898269 @default.
- W2061430101 hasConceptScore W2061430101C174256460 @default.
- W2061430101 hasConceptScore W2061430101C178790620 @default.
- W2061430101 hasConceptScore W2061430101C181500209 @default.
- W2061430101 hasConceptScore W2061430101C184779094 @default.
- W2061430101 hasConceptScore W2061430101C185592680 @default.
- W2061430101 hasConceptScore W2061430101C33062035 @default.