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- W2061439273 abstract "In this paper lithium borophosphate glasses and glass-ceramics in the system 0.75|xB2O3.(100−x)P2O5|.25Li2O.yFe2O3 with 0≤x≤100 mol.% and y=4 mol.%, were studied by X-ray powder diffraction, Mössbauer and infrared spectroscopy. All the samples in the system present a glass or glass-ceramic behavior which was confirmed by X-ray diffraction. From our Mössbauer analysis, high spin Fe2+ and Fe3+ in a distorted octahedral coordination are present in all samples. One can conclude that both iron ions are at sites of distorted octahedral coordination, acting as network modifiers (NWM) in a very broad site distribution, which is characteristic of an amorphous structural neighborhood. Such glasses and glass-ceramics containing nonlinear optical materials formed in a controlled crystallization process would be interesting candidates for applications in new nonlinear optical devices." @default.
- W2061439273 created "2016-06-24" @default.
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- W2061439273 date "2001-11-01" @default.
- W2061439273 modified "2023-10-09" @default.
- W2061439273 title "Structural studies of lithium triborate (LBO–LiB3O5) in borophosphate glass-ceramics" @default.
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- W2061439273 doi "https://doi.org/10.1016/s1466-6049(01)00172-6" @default.
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