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- W2061448049 abstract "Reaction of the ligand N , N ′-(1,2-phenylene)diisonicotinamide (pia) with metal(II) salts MSO 4 [M = Cu(II), Zn(II)] leads to the formation of two 2D coordination networks [(CuSO 4 )(pia) · 2CH 3 OH · H 2 O] n ( 1 ) and [(ZnSO 4 )(pia) · 2H 2 O] n ( 2 ). In the solid state of 1 the Cu(II) center adopt a five-coordination square pyramidal geometry, and the network is generated through the interconnection of the pia organic moieties by [Cu 2 (SO 4 ) 2 ] dimers resulting in a 2D motif containing irregular inner cavities for guest molecule inclusion; in the case of 2 , the Zn(II) center adopt a tetrahedral coordination geometry and the 2D network is formed by pia with another type of connector, zigzag SO 4 2 - –Zn chains. Compound 2 displays intense photoluminescence in the solid state at room temperature upon photo-excitation at 245 nm. The photoluminescence behaviors of the polymer 2 are related to the intraligand emission excited state." @default.
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- W2061448049 date "2008-06-01" @default.
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- W2061448049 title "2D frameworks of Cu(II) and Zn(II) organo-metallic polymers self-assembled with N,N′-(1,2-phenylene)diisonicotinamide: Syntheses, structures, photoluminescence, and thermal properties" @default.
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- W2061448049 doi "https://doi.org/10.1016/j.ica.2007.11.001" @default.
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