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• W2061448286 abstract "Die oxidative Addition von Halogencyan an Pt(PPh3)4 liefert die gemischten trans-Cyanohalogeno-Komplexe (Ph3P)2Pt(X)CN 1a–c. In diesen kann Halogenid aufgrund des trans-Effekts der Cyanogruppe leicht durch andere anionische Liganden ausgetauscht werden. Die Azid- und Fulminatliganden in 1d und g sind besonders reaktiv und lassen sich unter milden Bedingungen in die Iso(thio)cyanato-Gruppe umwandeln. Der durch Cycloaddition von Acetonitril an die Azid-gruppe von 1 d gebildete Komplex 4 b enthält N1- und N2-gebundene 5-Methyltetrazolat-Liganden. Oberhalb 190°C wird eine N1 ⟷ N2 ⟷ N3 ⟷ N4-Fluktuation des koordinierten Tetrazolats festgestellt. Preparation and Reactivity of trans-Cyano(pseudo)halogenobis(triphenylphosphine)platin(II). Complexes The oxidative addition of cyanogen halides to Pt(PPh3)4 affords the mixed trans-cyanohalogeno complexes (Ph3P)2Pt(X)CN 1a–c. In these complexes the halide ligands can be easily exchanged ⟷other anions due to the trans effect of the cyanide group. The azide and fulminate ligand of 1d and g can be converted under mild conditions into iso(thio)cyanato groups. The cycloadduct 4b of 1d and acetonitrile contains N1- and N2-bonded 5-methyltetrazolate ligands. Above 190°C fluxional exchange N1 ⟷ N2 ⟷ N 3 ⟷ N4 of the coordinated tetrazolate is observed." @default.
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• W2061448286 date "1975-10-01" @default.
• W2061448286 modified "2023-10-16" @default.
• W2061448286 title "Darstellung und Reaktionen von <i>trans</i> ‐Cyano(pseudo)halogeno‐bis(triphenylphosphin)platin(II)‐Komplexen" @default.
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• W2061448286 doi "https://doi.org/10.1002/cber.19751081024" @default.
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