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- W2061462057 abstract "A variety of chiral N -phosphinyl α-imino esters have been synthesized for the first time from ketoesters and phosphinylamide, which were then reduced by L-selectride to give the corresponding N -phosphinyl-protected α-amino esters. The reduction proceeded very well with excellent chemical yields (88–98%) as well as high diastereoselectivities (96:4 to 99:1). Some of these products could be obtained without column chromatography and recrystallization. The chiral phosphinyl auxiliary could be easily cleaved under acidic conditions." @default.
- W2061462057 created "2016-06-24" @default.
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- W2061462057 date "2014-03-13" @default.
- W2061462057 modified "2023-10-16" @default.
- W2061462057 title "Synthesis of chiral <i>N</i>-phosphinyl α-imino esters and their application in asymmetric synthesis of α-amino esters by reduction" @default.
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- W2061462057 doi "https://doi.org/10.3762/bjoc.10.57" @default.
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