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• W2061485114 abstract "A general method for the syntheses of dipalladium compounds having a singly bonded Pd26+ core and the formula R,S-cis-Pd2(C6H4PPh2)2(O2CR)2Cl2 is described. When the alkyl group in the carboxylate ligands is an electron donating group, the compounds are stable and the yields high. The Pd−Pd distances for the diamagnetic compounds with R = CF3 and CMe3 are 2.5434(4) and 2.5241(9) Å, respectively. Calculations at the DFT level suggest that the electronic configuration is σ2π4δ2δ*2π*4. These represent rare examples of palladium(III) compounds." @default.
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• W2061485114 date "2006-09-28" @default.
• W2061485114 modified "2023-10-16" @default.
• W2061485114 title "High Yield Syntheses of Stable, Singly Bonded Pd₂⁶⁺ Compounds" @default.
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• W2061485114 doi "https://doi.org/10.1021/ja0656595" @default.
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