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• W2061491645 abstract "The very unusual structural features observed in the recently characterized high pressure novel K-Ag alloys can be rationalized using simple electron counting rules and a moment analysis of the electronic density of states. The stability of the alloys is attributed to almost complete electron transfer from K $4s$ bands to Ag $5s$ bands and spatially extended Ag $5p$ bands. This allows for efficient Ag-Ag bonding interactions at an unusually long distance of 5.54 AA{} and exceptionally short K-K bonds due to reduced repulsive interactions between the ${mathrm{K}}^{+}$ ions. The general principles developed here are applicable to the understanding of the structure and bonding of other high pressure intermetallic alloys." @default.
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• W2061491645 date "1999-05-31" @default.
• W2061491645 modified "2023-10-06" @default.
• W2061491645 title "Phase Stability and Electronic Structure of K-Ag Intermetallics at High Pressure" @default.
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• W2061491645 doi "https://doi.org/10.1103/physrevlett.82.4472" @default.
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