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• W2061506657 abstract "The key, versatile precursors N2-(N,N-dimethylaminomethylene)-1′-O-(4-methoxybenzyl)-3-[2-(4-nitrophenyl)ethyl]biopterin (29a) and its ciliapterin analog (29b) were prepared, respectively, from d-xylose (in 14 steps) and l-xylose (in 11 steps). Treatment of 29a and 29b with 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-d-glucopyranosyl bromide in the presence of silver triflate and tetramethylurea, followed by removal of the protecting groups, led to the first selective syntheses of limipterin (3) and tepidopterin (5), respectively." @default.
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• W2061506657 date "2008-02-01" @default.
• W2061506657 modified "2023-10-18" @default.
• W2061506657 title "Efficient total syntheses of natural pterin glycosides: limipterin and tepidopterin" @default.
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• W2061506657 doi "https://doi.org/10.1016/j.tet.2007.12.042" @default.
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