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• W2061544423 abstract "η3-Allyliridium(III) complexes Cp*Ir(η3-CHPhCHCH2)(−C⋮C-t-Bu) (2), Cp*Ir(η3-CHPhCHCH−CHCH(t-Bu))Cl (3H), Cp*Ir(η3-CHPhCHCH−CHCMe(t-Bu))I (3Me), [Cp*Ir(η3-CHPhCHCH−CHCMe(t-Bu))(NCMe)]+ (4), and Cp*Ir(η3-CHPhCHCH−CHCMe(t-Bu))(−C⋮C-t-Bu‘) (5) have been prepared from the reactions of [Cp*Ir(η3-CHPhCHCH2)(NCMe)]+ (1) with H−C⋮C-t-Bu (in the presence of NEt3), HCl, and MeI. The crystal structures of 2 and 5 have been determined by X-ray diffraction data analyses. Reactions of 3 and 5 with HCl produce trans,trans-1,3-pentadienes, PhCHCHCHCHCH2(t-Bu) (6H) and PhCHCHCHCHCHMe(t-Bu) (6Me), and cis,trans,trans-1,3,5-heptatriene, (t-Bu‘)CHCHC(Ph)CHCHCHCHMe(t-Bu) (8), respectively." @default.
• W2061544423 created "2016-06-24" @default.
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• W2061544423 date "1999-05-01" @default.
• W2061544423 modified "2023-10-11" @default.
• W2061544423 title "Electrophile (H⁺, Me⁺)-Mediated Carbon−Carbon Bond Formation between η³-Allyl and Alkynyl Groups Coordinated to “Cp*Ir”" @default.
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• W2061544423 doi "https://doi.org/10.1021/om9900770" @default.
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