Matches in SemOpenAlex for { <https://semopenalex.org/work/W2061555712> ?p ?o ?g. }
Showing items 1 to 88 of
88
with 100 items per page.
- W2061555712 endingPage "5102" @default.
- W2061555712 startingPage "5097" @default.
- W2061555712 abstract "In this paper, the construction and performance of a rugged device for postcolumn derivatization in capillary electrophoresis (CE) are described. The device was based on a gap design, and a gap with a very small distance (<3 μm, estimated under microscope) could be easily constructed without micromanipulation. Addition of derivatizing reagents into the reaction capillary was attributable to gravity flow. The concentration of derivatizing reagents can be controlled through manipulating the electroosmotic flow in the reaction capillary and the height of the liquid levels from the derivatizing reagents to the buffer reservoirs. The device has been applied in fluorescence detection of amino acids using a mixture of o-phthaldialdehyde/2-mercaptoethanol as derivatizing reagent. Theoretical plate numbers for 11 amino acids separated in a pH 9.5 borate buffer were obtained in the order of 40 000-250 000. The detection limit for glycine (S/N = 2) was found to be 6.7 × 10(-)(7) mol/L using a commercial HPLC fluorescence detector modified for CE. Free amino acids in a wine sample were also determined. Because the device is quite stable, we believe that it can be used routinely in analytical laboratories." @default.
- W2061555712 created "2016-06-24" @default.
- W2061555712 creator A5027877032 @default.
- W2061555712 creator A5090543024 @default.
- W2061555712 date "1998-10-24" @default.
- W2061555712 modified "2023-10-18" @default.
- W2061555712 title "Rugged Gap Reactor Device for Postcolumn Fluorescence Detection in Capillary Electrophoresis" @default.
- W2061555712 cites W1540171446 @default.
- W2061555712 cites W1974295416 @default.
- W2061555712 cites W1979809757 @default.
- W2061555712 cites W1997890062 @default.
- W2061555712 cites W2005252365 @default.
- W2061555712 cites W2027332376 @default.
- W2061555712 cites W2032887265 @default.
- W2061555712 cites W2036719946 @default.
- W2061555712 cites W2047395789 @default.
- W2061555712 cites W2070182455 @default.
- W2061555712 cites W2089459067 @default.
- W2061555712 cites W2094097453 @default.
- W2061555712 cites W4231793847 @default.
- W2061555712 doi "https://doi.org/10.1021/ac980561x" @default.
- W2061555712 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21644687" @default.
- W2061555712 hasPublicationYear "1998" @default.
- W2061555712 type Work @default.
- W2061555712 sameAs 2061555712 @default.
- W2061555712 citedByCount "10" @default.
- W2061555712 countsByYear W20615557122013 @default.
- W2061555712 countsByYear W20615557122016 @default.
- W2061555712 countsByYear W20615557122020 @default.
- W2061555712 crossrefType "journal-article" @default.
- W2061555712 hasAuthorship W2061555712A5027877032 @default.
- W2061555712 hasAuthorship W2061555712A5090543024 @default.
- W2061555712 hasConcept C113196181 @default.
- W2061555712 hasConcept C119128265 @default.
- W2061555712 hasConcept C121332964 @default.
- W2061555712 hasConcept C159985019 @default.
- W2061555712 hasConcept C178790620 @default.
- W2061555712 hasConcept C179998833 @default.
- W2061555712 hasConcept C185592680 @default.
- W2061555712 hasConcept C192562407 @default.
- W2061555712 hasConcept C196806460 @default.
- W2061555712 hasConcept C2776923573 @default.
- W2061555712 hasConcept C2900643 @default.
- W2061555712 hasConcept C40875361 @default.
- W2061555712 hasConcept C43617362 @default.
- W2061555712 hasConcept C515207424 @default.
- W2061555712 hasConcept C55493867 @default.
- W2061555712 hasConcept C62520636 @default.
- W2061555712 hasConcept C91881484 @default.
- W2061555712 hasConceptScore W2061555712C113196181 @default.
- W2061555712 hasConceptScore W2061555712C119128265 @default.
- W2061555712 hasConceptScore W2061555712C121332964 @default.
- W2061555712 hasConceptScore W2061555712C159985019 @default.
- W2061555712 hasConceptScore W2061555712C178790620 @default.
- W2061555712 hasConceptScore W2061555712C179998833 @default.
- W2061555712 hasConceptScore W2061555712C185592680 @default.
- W2061555712 hasConceptScore W2061555712C192562407 @default.
- W2061555712 hasConceptScore W2061555712C196806460 @default.
- W2061555712 hasConceptScore W2061555712C2776923573 @default.
- W2061555712 hasConceptScore W2061555712C2900643 @default.
- W2061555712 hasConceptScore W2061555712C40875361 @default.
- W2061555712 hasConceptScore W2061555712C43617362 @default.
- W2061555712 hasConceptScore W2061555712C515207424 @default.
- W2061555712 hasConceptScore W2061555712C55493867 @default.
- W2061555712 hasConceptScore W2061555712C62520636 @default.
- W2061555712 hasConceptScore W2061555712C91881484 @default.
- W2061555712 hasIssue "23" @default.
- W2061555712 hasLocation W20615557121 @default.
- W2061555712 hasLocation W20615557122 @default.
- W2061555712 hasOpenAccess W2061555712 @default.
- W2061555712 hasPrimaryLocation W20615557121 @default.
- W2061555712 hasRelatedWork W1968781128 @default.
- W2061555712 hasRelatedWork W2052658201 @default.
- W2061555712 hasRelatedWork W2053273822 @default.
- W2061555712 hasRelatedWork W2063401993 @default.
- W2061555712 hasRelatedWork W2065377794 @default.
- W2061555712 hasRelatedWork W2084062459 @default.
- W2061555712 hasRelatedWork W2086107997 @default.
- W2061555712 hasRelatedWork W2086962581 @default.
- W2061555712 hasRelatedWork W2096641431 @default.
- W2061555712 hasRelatedWork W2109029516 @default.
- W2061555712 hasVolume "70" @default.
- W2061555712 isParatext "false" @default.
- W2061555712 isRetracted "false" @default.
- W2061555712 magId "2061555712" @default.
- W2061555712 workType "article" @default.