FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2061556443> ?p ?o ?g. }

• W2061556443 endingPage "846" @default.
• W2061556443 startingPage "838" @default.
• W2061556443 abstract "A hybrid copolymer [poly(ethylene glycol dimethacrylate-co-protoporphyrin)-silica], synthesized by free radical copolymerization and sol–gel process was evaluated as novel adsorbent for solid-phase extraction of Cd2+ ions. Characterization of hybrid polymer was performed by FTIR, SEM and surface area analyzes. Adsorption isotherms built at pH 8.9 were very well adjusted (R2 = 0.9982) to hybrid non-linear Langmuir–Freundlich model for two sites, indicating the existence of different affinity constants for binding sites, which was confirmed by Scatchard plot. The estimated maximum adsorption capacity was found to be 8.28 mg g−1. The adsorption kinetics data also corroborated to the isotherm, where the Cd2+ ions adsorption followed the pseudo-second-order kinetic (R2 = 0.998). The on-line preconcentration procedure, optimized by means of factorial designs, was based on sample preconcentration (16 mL) at pH 8.9 through 50.0 mg of hybrid copolymer packed in mini-column at 8.0 mL min−1 flow rate. The on-line desorption of Cd2+ ions towards the FAAS detector was carried out in countercurrent at 5.0 mL min−1 flow rate using 0.8 mol L−1 HNO3. Using the on-line preconcentration procedure, the maximum adsorption capacity determined from breakthrough curve was found to be 2.25 mg g−1. Analytical curve ranged from 0.0 up to 50.0 μg L−1 (r = 0.997), limit of detection of 0.27 μg L−1, preconcentration factor of 38.4, sample throughput of 30 h−1 and consumptive index of 0.41 mL, were achieved. The preconcentration method, very tolerable to several foreign ions, was successfully applied to the Cd2+ ions determination in water samples and cigarette sample. The accuracy was checked from analysis of certified reference materials." @default.
• W2061556443 created "2016-06-24" @default.
• W2061556443 creator A5000926287 @default.
• W2061556443 creator A5002218859 @default.
• W2061556443 creator A5066235730 @default.
• W2061556443 date "2013-06-01" @default.
• W2061556443 modified "2023-10-03" @default.
• W2061556443 title "Synthesis and adsorption studies of novel hybrid mesoporous copolymer functionalized with protoporphyrin for batch and on-line solid-phase extraction of Cd2+ ions" @default.
• W2061556443 cites W1964447320 @default.
• W2061556443 cites W1965631747 @default.
• W2061556443 cites W1967793379 @default.
• W2061556443 cites W1968363725 @default.
• W2061556443 cites W1972833752 @default.
• W2061556443 cites W1977198068 @default.
• W2061556443 cites W1978193115 @default.
• W2061556443 cites W1982886468 @default.
• W2061556443 cites W1984604841 @default.
• W2061556443 cites W1985998615 @default.
• W2061556443 cites W1990215025 @default.
• W2061556443 cites W1990310567 @default.
• W2061556443 cites W1994769873 @default.
• W2061556443 cites W1996822951 @default.
• W2061556443 cites W1997587486 @default.
• W2061556443 cites W1999918683 @default.
• W2061556443 cites W2000103797 @default.
• W2061556443 cites W2000141214 @default.
• W2061556443 cites W2001154000 @default.
• W2061556443 cites W2002307630 @default.
• W2061556443 cites W2003964280 @default.
• W2061556443 cites W2007797328 @default.
• W2061556443 cites W2007838100 @default.
• W2061556443 cites W2008267005 @default.
• W2061556443 cites W2009332024 @default.
• W2061556443 cites W2013279913 @default.
• W2061556443 cites W2015637447 @default.
• W2061556443 cites W2022002954 @default.
• W2061556443 cites W2029400623 @default.
• W2061556443 cites W2031220324 @default.
• W2061556443 cites W2033570186 @default.
• W2061556443 cites W2043004096 @default.
• W2061556443 cites W2044039366 @default.
• W2061556443 cites W2045579212 @default.
• W2061556443 cites W2048034917 @default.
• W2061556443 cites W2050575076 @default.
• W2061556443 cites W2057670879 @default.
• W2061556443 cites W2060227504 @default.
• W2061556443 cites W2065658481 @default.
• W2061556443 cites W2069426231 @default.
• W2061556443 cites W2070195824 @default.
• W2061556443 cites W2074041088 @default.
• W2061556443 cites W2094144134 @default.
• W2061556443 cites W2094712774 @default.
• W2061556443 cites W2095385714 @default.
• W2061556443 cites W2096926846 @default.
• W2061556443 cites W2104174988 @default.
• W2061556443 cites W2131602139 @default.
• W2061556443 cites W2131778071 @default.
• W2061556443 cites W2133903756 @default.
• W2061556443 cites W2136195365 @default.
• W2061556443 cites W2147462172 @default.
• W2061556443 cites W2166838628 @default.
• W2061556443 cites W2557168143 @default.
• W2061556443 doi "https://doi.org/10.1016/j.reactfunctpolym.2013.03.017" @default.
• W2061556443 hasPublicationYear "2013" @default.
• W2061556443 type Work @default.
• W2061556443 sameAs 2061556443 @default.
• W2061556443 citedByCount "23" @default.
• W2061556443 countsByYear W20615564432014 @default.
• W2061556443 countsByYear W20615564432015 @default.
• W2061556443 countsByYear W20615564432016 @default.
• W2061556443 countsByYear W20615564432017 @default.
• W2061556443 countsByYear W20615564432018 @default.
• W2061556443 countsByYear W20615564432019 @default.
• W2061556443 countsByYear W20615564432021 @default.
• W2061556443 countsByYear W20615564432023 @default.
• W2061556443 crossrefType "journal-article" @default.
• W2061556443 hasAuthorship W2061556443A5000926287 @default.
• W2061556443 hasAuthorship W2061556443A5002218859 @default.
• W2061556443 hasAuthorship W2061556443A5066235730 @default.
• W2061556443 hasConcept C112825004 @default.
• W2061556443 hasConcept C113196181 @default.
• W2061556443 hasConcept C115958267 @default.
• W2061556443 hasConcept C119128265 @default.
• W2061556443 hasConcept C12143843 @default.
• W2061556443 hasConcept C13965031 @default.
• W2061556443 hasConcept C150394285 @default.
• W2061556443 hasConcept C15920480 @default.
• W2061556443 hasConcept C162711632 @default.
• W2061556443 hasConcept C178790620 @default.
• W2061556443 hasConcept C185592680 @default.
• W2061556443 hasConcept C43617362 @default.
• W2061556443 hasConcept C4725764 @default.
• W2061556443 hasConcept C521977710 @default.
• W2061556443 hasConcept C81426234 @default.
• W2061556443 hasConceptScore W2061556443C112825004 @default.
• W2061556443 hasConceptScore W2061556443C113196181 @default.
• W2061556443 hasConceptScore W2061556443C115958267 @default.
• W2061556443 hasConceptScore W2061556443C119128265 @default.

• next