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- W2061567353 abstract "Values of partial molar volumes at infinite dilution of 9 inorganic and 4 organic 1:1 electrolytes have been determined in (water + ethylammonium nitrate) (EAN) binary at 298.15 K throughout the composition scale. Our theoretical analysis shows that the values of partial molar volumes at infinite dilution of a solute in a binary are linked to those of the partial molar volumes of the components of mixed solvent. This applies to mixtures of molecular solvents as well as (water + ionic liquid) media. The use of the “pseudo-lattice theory” of Bahe recently supplemented Varela can be used for calculations and to obtain information about the interactions between 1:1 electrolytes as solutes at infinite dilution and their concentrated saline environment. We show that the “pseudo-lattice theory” allows accurate description of the behaviours of symmetrical tetraalkylammoniums bromide between the infinitely dilute state and concentrations higher than 2 mol · L−1." @default.
- W2061567353 created "2016-06-24" @default.
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- W2061567353 date "2008-02-01" @default.
- W2061567353 modified "2023-09-25" @default.
- W2061567353 title "Part 2: Limiting apparent molar volume of organic and inorganic 1:1 electrolytes in (water+ethylammonium nitrate) mixtures at 298K – Thermodynamic approach using Bahe–Varela pseudo-lattice theory" @default.
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- W2061567353 doi "https://doi.org/10.1016/j.jct.2007.07.008" @default.
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