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• W2061600539 abstract "CoSb3 with the skutterudite-type structure was synthesized by solid-state reaction and the atom insertion into the body-centered vacant site was attempted under high pressure and temperature conditions. Various 14-group elements were selected for atom insertion under pressure of 30 MPa to 5 GPa. It was found that various elements could be inserted in the body-centered vacant site, resulting in the formation of new filled-skutterudite phase MxCo4Sb12 (M=Si, Ge, Sn, Pb). The degree of insertion (x) increased with increasing the applied pressure. In the case of the Sn–CoSb3 system, nearly 40% of the body-centered vacant site was filled by Sn atom at 5 GPa. The crystal structure of resulting Sn0.4Co4Sb12 was refined by the Rietveld analysis of the X-ray diffraction data." @default.
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• W2061600539 date "1999-01-01" @default.
• W2061600539 modified "2023-09-26" @default.
• W2061600539 title "Atom insertion into the CoSb3 skutterudite host lattice under high pressure" @default.
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• W2061600539 doi "https://doi.org/10.1016/s0925-8388(98)00802-0" @default.
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