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- W2061614917 abstract "Equilibrium constants of a fundamental reaction of the aluminium subhalide process, 2Al(l)+AlCl3(g)=3AlCl(g), were determined by the flow method using argon carrier between 1000°C and 1250°C. As a result of this experiment, equilibrium constants and standard free energy were obtained by the following equation:logKp(=P3AlCl⁄PAlCl3)=−14,440⁄T+9.87ΔG0T=66,060−45.16T.The heat of formation and entropy of AlCl(g) obtained from the experimental data and other thermodynamic values were −22,250 cal/mol and 48.7 cal/mol respectively. By the use of the equilibrium constants, the reaction ratio of aluminium trichloride was calculated at a reduced pressure and in argon carrier, respectively." @default.
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- W2061614917 date "1964-01-01" @default.
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- W2061614917 title "Equilibrium of the 2Al(l)+AlCl<SUB>3</SUB>(g)=3AlCl(g) Reaction in the Subhalide Process of Aluminium (Study of Extractive Metallurgy of Aluminium (1))" @default.
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- W2061614917 doi "https://doi.org/10.2320/matertrans1960.5.122" @default.
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