Matches in SemOpenAlex for { <https://semopenalex.org/work/W2061661408> ?p ?o ?g. }
- W2061661408 abstract "A new anion photoelectron (PE) spectrum of WC− is presented and analyzed using existing and new calculations. This spectrum is different from the PE spectrum previously published [X. Li et al., J. Chem. Phys. 111, 2464 (1999)], which we suggest was actually the PE spectrum of W−. The ground anion state is determined by calculations and comparison with spectral features to be the Δ3∕22 state. The Δ13−Δ3∕22 transition is observed at an electron binding energy of 2.155eV, which corresponds to the adiabatic electron affinity of WC. The bond length of the anion is determined to be 1.771(5)Å. A number of spectral assignments corresponding to both excited anion and neutral states are made based on previously obtained fluorescence spectra [S. M. Sickafoose et al., J. Chem. Phys. 116, 993 (2002)] and density functional theory calculations." @default.
- W2061661408 created "2016-06-24" @default.
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- W2061661408 date "2008-09-16" @default.
- W2061661408 modified "2023-09-26" @default.
- W2061661408 title "Tungsten carbide revisited: New anion photoelectron spectrum and density functional theory calculations" @default.
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- W2061661408 doi "https://doi.org/10.1063/1.2976342" @default.
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