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• W2061663824 startingPage "1151" @default.
• W2061663824 abstract "Excess molar heat capacities Cp, mEat constant pressure have been measured, as a function of mole fraction x at the temperature T = 298.15 K and atmospheric pressure, for eight liquid mixtures consisting of an n -alkylalkanoate and a highly-branched alkane {i.e. 2,2,4-trimethylpentane (isooctane) and 2,2,4,4,6,8,8-heptamethyl- nonane}: [xHCOO(CH2)3CH3 + (1 − x){(CH3)3CCH2CH(CH3)2, or (CH3)3CCH2C(CH3)2CH2CH(CH3)CH2C(CH3)3} ], {xCH3COOCH2CH3 + (1 − x)(CH3)3CCH2CH(CH3)2}, {xCH3COO(CH2)3CH3 + (1 − x)(CH3)3CCH2CH(CH3)2}, {xCH3CH2COOCH3 + (1 − x)(CH3)3CCH2CH(CH3)2}, [xCH3CH2COOCH2CH3 + (1 − x){(CH3)3CCH2CH(CH3)2, or (CH3)3CCH2C(CH3)2CH2CH(CH3)CH2C(CH3)3}], {xCH3CH2COO(CH2)2CH3 + (1 − x)(CH3)3CCH2CH(CH3)2}. Excess molar volumes VmEhave been determined, as a function of mole fraction x at the same temperature and pressure, for the same eight mixtures. The instruments used were a Picker flow microcalorimeter and a vibrating-tube densimeter, respectively. All the mixtures show positive excess volumes with a more or less parabolic composition dependence, with the maximum values of VmEranging between c. 0.3 cm3· mol − 1and 0.9 cm3· mol − 1. Most of the Cp, mEagainst x curves show a pronounced W-shape. However, for {xCH3CH2COO(CH2)2CH3 + (1 − x)(CH3)3CCH2CH(CH3)2}, the Cp, mEcurve has degenerated to one with a virtually flat portion extending from about x = 0.2 to x = 0.8, and Cp, mEof {xHCOO(CH2)3CH3 + (1 − x)(CH3)3CCH2CH(CH3)2} is S-shaped with the negative part situated at small mole fractions of n -butylmethanoate." @default.
• W2061663824 created "2016-06-24" @default.
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• W2061663824 date "1999-09-01" @default.
• W2061663824 modified "2023-09-24" @default.
• W2061663824 title "Excess molar heat capacities and excess molar volumes of (ann-alkylalkanoate + 2,2,4-trimethylpentane, or 2,2,4,4,6,8,8-heptamethylnonane) atT= 298.15 K" @default.
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• W2061663824 doi "https://doi.org/10.1006/jcht.1999.0530" @default.
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