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- W2061691775 abstract "The inhibition of the first limit of the hydrogen-oxygen reaction by ethyl bromide has beenstudied between 460° and 520°C, over a wide range of mixture composition, using clean Pyrex and silica reaction vessels. It is shown that the inhibition arises through the reactions: H+C2H5Br=HBr+C2H5, (5) C2H5+O2=C2H4+HO2, (7) The surface-destruction constants for the removal of hydrogen and oxygen atoms by the surface have been determined from a detailed analysis of the uninhibited-explosion pressures, and these values have been used to calculate a value of k5 from each inhibited-explosion pressure. These values are independent of mixture composition and vessel diameter, and an Arrhenius plot gives logk5/cm3 mole−1s−1=(13.93±0.24)−(5470±830)/4.576T. No evidence was obtained for any reaction of hydroxyl radicals or oxygen atoms with the ethyl bromide, and the implications of these results to the problem of flame inhibition by halogen compounds is considered." @default.
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- W2061691775 date "1973-01-01" @default.
- W2061691775 modified "2023-09-23" @default.
- W2061691775 title "Inhibition of the first limit of the hydrogen-oxygen reaction by ethyl bromide" @default.
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- W2061691775 doi "https://doi.org/10.1016/s0082-0784(73)80043-8" @default.
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